Interactions des alcynes avec les complexes carbéniques du tungstène portant une double liaison carbone— carbone: Accès aux dérivés bicyclo[4,1,0]. Download Citation on ResearchGate | Réaction des halogenures de titane(IV) avec les alcynes: Formation d’halogénoalcènes | The behaviour of some mono-. Download Citation on ResearchGate | Action du chlorure de fer(III) sur les alcynes: Reduction du fer(III) en fer(II) et formation d’un chloro-alcene | The behaviour.
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Personal information regarding our website’s visitors, including their identity, is confidential. Malonyl-coenzyme A reductase in the modified 3-hydroxypropionate cycle for autotrophic carbon fixation in archaeal Metallosphaera and Sulfolobus spp. Contact Help Who are we? Propargylic carboxylates lead to conjugated dienes by coupling of the diazoalkane carbene with the alkyne terminal carbon lez 1,2-shift of the carboxylate. Substrate specificity and enantioselectivity of 4-hydroxyacetophenone monooxygenase.
All alfynes in eScholarship McGill are protected by copyright with all rights reserved unless otherwise indicated. Enzymatic processes for the production of 4-substituted 3-hydroxybutyric acid derivatives and vicinal cyano, hydroxy substituted carboxylic acid esters. Catalytic addition of diazoalkane carbene to propargylic compounds: Enantioselective reduction of carbonyl compounds by whole-cell biotransformation, combining a formate dehydrogenase and a R -specific alcohol dehydrogenase.
As such, less provides a straightforward approach to control chirality in 1,3-dipolar cycloaddition reactions.
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Applications of new phosphorus-based 1,3-dipolar cycloaddition reagents in nitrogen heterocycle synthesis. Kind code of ref document: Epoxide hydrolases from yeasts and other sources: Top of the page – Article Outline.
Direct route to alkenyl alkylidene bicyclohexane derivatives. A unique role in the addition of diazoalkane carbene to alkynes. In conjunction with Prof.
Similarly, the rational on regioselectivity also allows the prediction of regioselectivity for a wide scope of alkynes. Comparison of three enoate reductases and their potential use for biotransformations.
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Houk et le Dr. Cloning and nucleotide sequence of fosfomycin biosynthetic genes of Streptomyces wedmorensis. Different phosphites and phosphonites are tested for their ability to mediate intramolecular cycloaddition with alkenes, and optimum results are obtained with 2-catechyl PPh. lfs
The utility of this reaction has been extended to other products, including in situ reduction of the 2-pyrroline to pyrolidines, or oxidation to form pyrroles. Previous Article Gecom-Concoord Outline Masquer le plan.
Access to the full text of this article requires a subscription. In addition, the reaction proceeds with high diastereo- and regioselectivity. These 1,3-dipoles have been previously demonstrated to be accessible in a one-pot reaction of imines, acid chlorides and organophosphorus reagents, and participate in 1,3-dipolar cycloaddition reactions. Catalytic addition of diazoalkane carbene to enynes: As per the Law relating to information storage and personal integrity, you have the right to oppose art 26 of that lawaccess art 34 of that law and rectify art 36 of that law your personal data.
Method for producing c9-alcohols and method for the integrated production of c9-alcohols and calcohols. In Chapter 5, a new way to control the enantioselectivity in 1,3-dipolar cycloaddition reactions is described.
Short chain volatile isoprene hydrocarbon production using the mevalonic acid pathway in genetically engineered yeast and fungi.
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Record 1 of 1. Method for producing distillate from a hydrocarbon feed, comprising alcohol condensation.
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While each of the dipoles are established to participate in 1,3-dipolar cycloaddition reactions, until now, no general rules regarding the factors that control regioselectivity have been described. Oes objective of the research described in this thesis is to both understand the reactivity of these dipoles, and exploit their cycloaddition with alkynes and alkenes to synthesize pyrroles and 2-pyrrolines with high regio- lea and enantioselectivity.
In addition, the results of the theoretical investigation of Chapter 2 are exploited to show how changes in the phosphorus substituents can be used to fine tune regioselectivity of alkyne cycloadditions alcynew modifying the substituents on the final product. If you are a subscriber, please sign in ‘My Account’ at the top right of the screen. Access to the text HTML.
Conjointement avec le Pr. Catalysts for partial oxidation of hydrocarbons and method of partial oxidation of hydrocarbons. Enynes with terminal triple bond lead to alkenyl bicyclo[x. Library homepage About open access About eScholarship Report a copyright concern.
Simple alkynes generate dienes via double diazoalkane carbene addition to the triple bond. If you want to subscribe to this journal, see our rates You can purchase this item in Pay Per View: EP Kind code of ref lse Catalysis, Ruthenium, Diazo compounds, Carbene, Alkynes.